-------------------------------------------------------------- INSTITUTE OF FORENSIC RESEARCH In the name of Prof. Dr. Jan Sehn, Krakow Division of Forensic Toxicology Krakow, 24 Sept. 1990 Westerplatte 9 / Code 31-033 Tel. 505-44, 592-24, 287-50 Telex 0325213 eksad ... The hydrocyanic acid (HCN) that is released from the Zyklon B preparation is a liquid with a boiling point of about 27 degrees Celsius. It has an acidic character, and therefore forms compounds with metallic salts, which are known as cyanides. The salts of alkaline metals (such as sodium and potassium) are water soluble. Hydrocyanic acid is a very weak acid, and accordingly its salts dissolve easily in stronger acids. Even carbonic acid, which is formed as a reaction of carbon dioxide with water, will dissolve ferro-cyanide. Stronger acids, such as sulfuric acids, easily dissolve the cyanides. The compounds of cyanide ions with heavy metals are longer lasting. This includes the already mentioned Prussian blue, although this will also slowly dissolve in an acidic environment. Therefore, one can hardly assume that traces of cyanic compounds could still be detected in construction materials (plaster, brick) after 45 years, after being subjected to the weather and the elements (rain, acid oxides, especially sulfuric and nitrogen oxides). More reliable would be the analysis of wall plaster [samples] from closed rooms which were not subject to weather and the elements (including acid rain). The discovery of hydrocyanic acid compounds in samples of material which had been subject to the elements can only be accidental. --------------------------------------------------------------
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